2nd Edition

Introduction to Polymer Science and Chemistry A Problem-Solving Approach, Second Edition

By Manas Chanda Copyright 2013
    770 Pages 240 B/W Illustrations
    by CRC Press

    Industry and academia remain fascinated with the diverse properties and applications of polymers. However, most introductory books on this enormous and important field do not stress practical problem solving or include recent advances, which are critical for the modern polymer scientist-to-be. Updating the popular first edition of "the polymer book for the new millennium," Introduction to Polymer Science and Chemistry: A Problem-Solving Approach, Second Edition seamlessly integrates exploration of the fundamentals of polymer science and polymer chemistry.

    See What’s New in the Second Edition:

    • Chapter on living/controlled radical polymerization, using a unique problem-solving approach
    • Chapter on polymer synthesis by "click" chemistry, using a unique problem-solving approach
    • Relevant and practical work-out problems and case studies
    • Examples of novel methods of synthesis of complex polymer molecules by exciting new techniques
    • Figures and schematics of the novel synthetic pathways described in the new examples

    Author Manas Chanda takes an innovative problem-solving approach in which the text presents worked-out problems or questions with answers at every step of the development of a new theory or concept, ensuring a better grasp of the subject and scope for self study. Containing 286 text-embedded solved problems and 277 end-of-chapter home-study problems (fully answered separately in a Solutions Manual), the book provides a comprehensive understanding of the subject. These features and more set this book apart from other currently available polymer chemistry texts.

    Introductory Concepts
    Basic Definitions
    Polymerization and Functionality
    Polymerization Processes
    Molecular Architecture
    Classification of Polymers
    Plastics, Fibers, and Elastomers
    Polymer Nomenclature
    References
    Exercises

    Chain Dimensions, Structures, and Transitional
    Phenomena
    Introduction
    PolymerChains: Structures and Dimensions
    Constitutional and Configurational Isomerism
    Crystallinity in Polymers
    Thermal Transitions in Polymers
    Regions of Viscoelastic Behavior
    Factors Affecting Tg
    Factors Affecting Tm
    Relation Between Tm and Tg
    Theoretical Treatment of Glass Transition
    Chain Movements in Amorphous State
    Thermodynamics of Rubber Elasticity
    References
    Exercises

    Polymers in Solution
    Introduction
    Phase Equilibria in Poor Solvents
    Solubility Behavior of Polymers
    Swelling of Crosslinked Polymers
    Frictional Properties of Polymer Molecules in Dilute Solution
    References
    Exercises

    Polymer Molecular Weights
    Introduction
    Molecular Weight Averages
    Molecular Weights in Terms of Moments
    Molecular Weight Determination
    References
    Exercises

    Condensation (Step-Growth) Polymerization
    Introduction
    Rates of Polycondensation Reactions
    Number-Average Degree of Polymerization
    Control of Molecular Weight
    Molecular Weight Distribution (MWD)
    Nonlinear Step Polymerization
    Recursive Approach for Average Properties
    Polycondensation of AxB Monomers
    References
    Exercises

    Free Radical Polymerization
    Introduction
    Scheme of Radical Chain Polymerization
    Experimental Determination of Rp : Dilatometry
    Methods of Initiation
    Dead-End Polymerization
    Determination of Absolute Rate Constants
    Chain Length and Degree of Polymerization
    Chain Transfer
    Deviations from Ideal Kinetics
    Inhibition/Retardation of Polymerization
    Effects of Temperature
    Molecular Weight Distribution
    Polymerization Processes
    Living Radical Polymerization
    References
    Exercises

    Chain Copolymerization
    Introduction
    Binary Copolymer Composition – Terminal Model
    Multicomponent Copolymerization: Terpolymerization
    Deviations from Terminal Model
    Copolymerization and Crosslinking
    Block and Graft Copolymerization
    Reference
    Exercises

    Ionic Chain Polymerization
    Introduction
    Ionic Polymerizability of Monomers
    Anionic Polymerization
    Anionic Copolymerization
    Cationic Polymerization
    References
    Exercises

    Coordination Addition Polymerization
    Introduction
    Ziegler-Natta Catalysts
    Mechanism of Ziegler-Natta Polymerization
    Kinetics of Ziegler-Natta Polymerization
    Supported Metal Oxide Catalysts
    Ziegler-Natta Copolymerization
    Metallocene-Based Ziegler-Natta Catalysts
    Immobilized Metallocene Catalysts
    Oscillating Metallocene Catalysts
    References
    Exercises

    Ring-Opening Polymerization
    Introduction
    Polymerization Mechanism and Kinetics
    References
    Exercises

    Living/Controlled Radical Polymerization
    Introduction
    Stable Free Radical Polymerization
    Atom Transfer Radical Polymerization (ATRP)
    Degenerative Chain Transfer
    Reversible Addition-Fragmentation Chain Transfer
    References
    Exercises

    Polymer Synthesis by Click Chemistry
    Introduction
    Copper-Catalyzed Azide-Alkyne Cycloaddition
    Strain-Promoted Azide-Alkyne Coupling
    Diels-Alder Click Reactions
    Thiol-Ene Reactions
    References
    Exercises

    Appendix A Conversion of Units
    Appendix B Fundamental Constants
    Index

    Biography

    Manas Chanda

    Professor Chanda’s book provides comprehensive coverage of polymer science, with emphasis on quantitative aspects. Worked problems illustrate important concepts and provide the path toward solution in a clear manner. Traditional chain and step growth are covered along with the latest polymerization methods, including ATRP, RAFT, and other polymerization methods.
    —Kenneth J. Wynne, Virginia Commonwealth University